PC> Spread Needle (0/0/20/25/45)

45 is getting close to an arrest needle - arguably better than a hit spread as most enemies you need to paralyze have low evasion to begin with.

These work really well on casts vs anything with low ESP, but finding someone who wants and is willing to pay for that might be tough.
 
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For casts, once you hit 35hit on an SN, your activation rate is actually better because ata becomes the only factor. If anything a 45hit Needle Should be 60-70.
 
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